Oct 31, 2024 · ZIF-7, as a robust and promising adsorbent for selective removal of ethane from ethylene, was studied by applying targeted pre- and postsynthetic functionalization and hybridization strategies as to evaluate the effect on the intrinsic gate opening mechanism and optimize performance.

May 1, 2018 · ZIF-8, ZIF-L, ZIF-67 and ZIF-7 were successfully synthesized from fresh and recycled synthesis solutions with high purity and yield. The adjustment of pH and the metal ion to organic linker molar ratio of the mother liquor were crucial for the synthesis of next generation of the ZIF crystals through the recycling procedure.

Feb 17, 2014 · ZIF-7 (Zn(PhIm) 2, PhIm = benzimidazolate) was one of the earliest-reported ZIFs with a prototypical structure related to that of sodalite (SOD topology). In 2011, Aguado et al. compared ZIF-7’s X-ray diffraction patterns and CO 2 sorption isotherms.

Dec 1, 2019 · Zeolitic imidazolate framework ZIF-7 (Zn (bim) 2) is a prototypical one among different ZIFs, and it is formed by connecting Zn actions with benzimidazole (bim) anions. Single crystal X-Ray diffraction studies shows it has a sodalite (SOD) topology with a …

Jun 21, 2017 · The developed novel ZIF-7 structure with amino-function and the resulting nanocomposite membranes are very attractive for applications like natural-gas sweetening or biogas purification.

May 15, 2010 · ZIF-7 is formed by bridging benzimidazolate anions and zinc cations resulting in a sodalite (SOD) topology with a pore size of about 0.3 nm. The ZIF-7 membrane exhibited promising H 2 separation abilities.

Sep 16, 2023 · The adsorption of CO 2 on ZIF-7 indicates persisting flexibility for all particle size regimes; with the crystal size, its distribution, and morphology having a significant impact on both gate-opening and gate-closing pressures and slope of CO 2 adsorption isotherms.

Herein, the framework flexibility of ZIF-7, a typical MOF famous for its phase transition between wide-pore (ZIF-7-I) and narrow-pore (ZIF-7-II) forms on desolvation, was successfully hindered by embedding MOF nanocrystals in the rigid polymer matrix.

Abstract: Twelve zeolitic imidazolate frameworks (ZIFs; termed ZIF-1 to -12) have been synthesized as crystals by copolymerization of either Zn (II) (ZIF-1 to -4, -6 to -8, and -10 to -11) or Co (II) (ZIF-9 and -12) with imidazolate-type links.

Jul 26, 2023 · The adsorption of CO2 on ZIF-7 indicates persisting flexibility for all particle size regimes; with the crystal size, its distribution and morphology having a significant impact on both gate-opening and gate-closing pressures and slope of CO2 adsorption isotherms.