Nov 18, 1999 · Elemental microanalysis of the resulting colourless cubic crystals suggested that their formula was Zn 4 O (BDC) 3 · (DMF) 8 (C 6 H 5 Cl); here we call this material MOF-5, where MOF...

Jul 15, 2018 · In this work, rod-like metal-organic framework (MOF-5) nanomaterial was synthesized by a solvothermal method and applied to efficiently adsorb U (VI) from aqueous solutions.

MOF-5 with a Zn (II) cluster and terephthalic acid is a distinctive porous material among the metal–organic frameworks (MOFs), with unique physical, chemical and mechanical properties. MOF-5 based composites possess ample applications in modern chemistry.

Aug 14, 2023 · The homogeneous interface between MOF-5 and NTU-COF has been inspected at atomic resolution by a combination of cryogenic focused ion beam (cryo-FIB) and ultralow-dose (scanning) transmission electron microscope giving profound insight into the mechanism of assembly of the core–shell structure.

MOF-5 showed substantial H 2 uptake that increased linearly with pressure, giving 1.0 weight % at 20 bar . These findings demonstrate the potential of MOFs for H 2 storage applications.

Feb 1, 2009 · Metal–organic framework MOF-5 (Zn 4 O (BDC) 3), a microporous material with a high surface area and large pore volume, was synthesized by three approaches: direct mixing of triethylamine (TEA), slow diffusion of TEA, and solvothermal synthesis.

MOF-5 (sometimes called IRMOF-1) is a metal organic framework (MOF) formed from Zn 4 O with 1,4-benzodicarboxylic acid between the nodes. The spheres represent the pore size that can be used for gas storage.

Jan 24, 2019 · Nano-sized metal organic framework-5 (MOF-5) was prepared in the presence of triethylamine (TEA) via consecutive combination of ultrasound (US) and microwave irradiation (MW) methods by exploiting the benefit of obtaining MOF-5 in very short reaction times (∼2 min) and high yields (∼95%).

Solvothermal, non-solvothermal, electrochemical, microwave-assisted synthesis, and sonochemical processes are among the numerous synthesis methods that may be employed to generate MOF-5. This study aimed to appraise the methods employed for synthesizing MOF-5 and its various applications.

MOF-5, also called as IRMOF-1, is a zinc based metal-organic framework that is made up of [Zn 4 O] 6+ inorganic moiety as the vertex and benzene dicarboxylic acid as the bifunctional bridging ligand of the crystal (Civalleri et al., 2006).