2020年12月3日 · The Josiphos ligand family is arguably one of the most versatile classes of chiral ligands with a wide range of applications, including one of the two largest known …

2022年2月9日 · JosiPhos作为一种手性二茂铁膦配体已经广泛应用于药物合成中。 上世纪90年代，Togni在研究Hayashi报道的Au (I)催化的aldol反应时，制备了含有各种侧链的二茂铁类配体 …

2021年4月14日 · Air-stable enantiopure copper chloride complexes of Josiphos with Ar’=Ar’’ and Ar’≠Ar’’ were synthesised (Ar’/Ar’’=Ph and o-Tol) requiring just two one-pot reactions when …

2011年4月6日 · Discovery and Development of the Josiphos Ligand Family. Why Are Josiphos Ligands So Effective? Catalytic Profile of the Josiphos Ligand Family. Concluding Remarks

Topics in Catalysis - The various stages from the invention of a ligand class to its technical application are described and illustrated by the case history of the Solvias Josiphos ligands. …

Starting from ferrocene, we compile a synthetic route to an air- and moisture-stable copper(I)-Josiphos complex via enantiopure Ugi’s amine, providing a potential one-stop shop for the …

In this review we give a general analysis of the possible reasons and illustrate our hypothesis with the example of the Josiphos ligands as one example of. a privileged ligand. 1.1. Success …

2019年10月11日 · Convenient synthesis and useful application of a series of Josiphos-type binaphane ligands were described. The iridium complexes of these chiral diphosphines …

2025年1月27日 · (S)-(R)-JOSIPHOS (CAS 162291-02-3) information, including chemical properties, structure, melting point, boiling point, density, formula, molecular weight, uses, …

2005年10月17日 · We herein report the synthesis of JOSIPHOS derivatives using the new efficient three-component reaction, since this excellent ligand is a rewarding objective for …