
Dioximes: Synthesis and biomedical applications - ScienceDirect
2019年2月1日 · Dioximes have special properties as analytical reagents for transition metals. Dioximes complexation properties with metals were carried out by many investigations and these complexations showed a wide range of applications such as antimicrobial and theranostic agents.
对苯醌二肟 - 百度百科
对苯醌二肟,又名1,4-苯醌二肟,是一种有机化合物,化学式为C6H6N2O2,为淡黄色至棕色结晶性粉末,易溶于乙醇、乙酸、乙酸乙酯,溶于热水,不溶于冷水、苯和汽油,主要用作丁基胶、天然胶、丁苯胶等的硫化剂,还可用作分析试剂等。 2017年10月27日,世界卫生组织国际癌症研究机构公布的致癌物清单初步整理参考,对苯醌二肟在3类致癌物清单中。 [1] 主要用作丁基胶、天然胶、丁苯胶等的硫化剂,还可用作分析试剂等。 S36/37:Wear suitable protective clothing …
p-Benzoquinone dioxime | C6H6N2O2 | CID 7737 - PubChem
p-Benzoquinone dioxime | C6H6N2O2 | CID 7737 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
Dioximes: Synthesis and biomedical applications - PubMed
Dioximes have special properties as analytical reagents for transition metals. Dioximes complexation properties with metals were carried out by many investigations and these complexations showed a wide range of applications such as antimicrobial and theranostic agents.
Synthesis, radiolabeling and biological distribution of a new dioxime …
2017年6月6日 · A novel dioxime derivative (2E,2′E,3E,3′E)-3,3′-(pyrimidine-4,5-diylbis(azanylylidene))bis(butan-2-one)dioxime was synthesized with a yield of 65%. IR, elemental analysis, mass spectroscopy and 1 H-NMR were used to characterize the structure of the synthesized compound.
Synthesis, spectroscopic characterization, crystal structure and ...
2023年9月1日 · The copper(II) complex was prepared by reaction of the ligand with copper(II) perchlorate hexahydrate in methanol under constant stirring for 1 h at room temperature. The newly synthesized dioxime ligand and its Cu(II) complex were characterized by several analytical and spectroscopic methods.
Potential of Vitamin B6 Dioxime Analogues to Act as …
2022年11月2日 · New dioxime derivatives of vitamin B6, compounds 1–7, were prepared in two steps, but the synthesis was attempted in two ways. First, a pyridoxal monooxime was quaternized with 2-bromoacetophenones, and then an attempt was made to convert the carbonyl group between the two aromatic rings into an oxime group.
对苯醌二肟 | 105-11-3 - ChemicalBook
该品主要用于制造气囊、水胎、电线电缆的绝缘层、耐热垫圈等。 用量1-2份。 与氧化铅10-6份或促进剂DM4-2份配合。 对苯醌二肟是测定镍的试剂。 由苯酚亚硝化生成对亚硝基苯酚,经转位成对醌单肟,再与盐酸羟胺反应得该品。 在搅拌下,慢慢将苯酚溶于30%氢氧化钠溶液,在0℃与亚硝酸钠混合,再加入30%硫酸,使温度保持在7-8℃,搅拌1h。 滤出结晶,用水洗去酸性,得对亚硝基酚。 再经转位,与盐酸羟胺水溶液混合,加热至70℃进行肟化反应。 反应毕,过滤得对 …
One-Pot Synthesis of Dioxime Oxalates - MDPI
2022年10月26日 · Dioxime oxalates, a type of carbonyl oximes, are well-known as clean sources of iminyl radicals that undergo key organic chemistry transformations. A series of dioxime oxalates is reported in this manuscript, obtained by the reaction of the corresponding oximes with oxalyl chloride and Et3N at room temperature.
99mTc-dioxime was radio-synthesized with a high radio-chemical yield of 97.8 ± 0.5% and in vitro stability of 6 h under the optimum conditions. The preclinical evaluation of 99mTc-dioxime in solid tumor-bearing mice showed high accumulation in solid tumor cells with a high Target/Non-Target ratio of 5.14 at 30 min post-injection. This study