2016年2月17日 · Among the large family of metal–organic frameworks (MOFs), Zr-based MOFs, which exhibit rich structure types, outstanding stability, intriguing properties and functions, are foreseen as one of the most promising MOF materials for practical applications.

Zirconium-based MOFs (Zr-MOFs) are comparatively stable with low cytotoxicity and high drug-loading capacity. Therefore, Zr-MOFs and their composites have been thoroughly investigated for various bio-related applications such as drug delivery, anti-cancer activity, bio …

A modulator engineering strategy was proposed to prepare high connectivity Zr-MOF membrane. The influence of modulator concentration and acidity on membrane lattice was investigated. The resulting MOF membrane exhibited outstanding methanol/DMC separation performance.

2020年6月23日 · Zirconium metal–organic framework (Zr-MOF) materials with excellent ion adsorption capacities and efficient ion sieving properties are highly desirable for many important industrial separation applications.

In this work, a novel aggregation-induced emission (AIE)-active ligand, tetraphenylpyrazine (PTTBPC) is proposed and utilized for the first time to construct a Zr-MOF photocatalyst via coordination with stable Zr-oxo clusters.

In this Feature Article, we discuss the evolution of Zr- and Ti-based MOFs, giving a brief overview of their synthesis and structures. Furthermore, the catalytic uses of Zr- and Ti-based MOF materials in the previous 3–5 years have been highlighted.

2013年2月14日 · Six novel Zr (IV)- and Hf (IV)-based MOFs, namely DUT-67, DUT-68, and DUT-69 (DUT, Dresden University of Technology) were obtained using a modulated synthesis approach with the acetic acid as a modulator and the bent 2,5 …