2019年7月2日 · The untwisted Zr-BTB-FA nanosheets coated column showed significant separation performance with excellent selectivity for six groups of substituted aromatic isomers including ethylbenzene, xylene...

2024年7月1日 · Oligo-layer Zr-BTB nanosheets were loaded onto the support layer surface by pumping filtration to form a nanosheet interlayer, which modulated the amine monomer attachment and diffusion behavior through spatial site resistance and interactions, resulting in a thin and dense intact separation layer.

2014年7月7日 · The Zr 6 clusters were linked by BTB ligands to generate a 2D network of kgd topology. The interpenetrations among the 2D networks gave rise to a 3D porous framework, which represents the first Zr MOF constructed from 2D → 3D interpenetration. The gas uptake and catalytic properties for 1 have also been studied.

2019年9月2日 · 通过高分辨率透射电镜（HRTEM）探究了相邻层间二维金属有机骨架纳米片（2-D MOFs nanosheets）Zr-BTB（1,3,5-三 ( 4-羧基苯基)苯）的堆叠模式，揭示了该纳米片随机堆叠的三种具有代表性的扭转角度。 简单高效的加热处理过程可以使纳米片规整堆叠，并展现出的亚纳米级孔径和层层堆叠结构；其涂覆的毛细管气相色谱柱可以高效分离取代苯结构异构体，对于间位/对位异构体的分离度不仅优于相应的扭曲堆叠纳米片柱，更优于不同极性的商业化柱。 这一发 …

2023年9月1日 · Quasi-Zr-BTB@CNTs based composite microflowers with the rich unsaturated Zr-O coordination of the Zr 6 node is successfully realized as efficient sulfur redox electrocatalysts. The well-designed deligandation strategy subtly modulates the local environment and electronic structure towards enhanced chemical affinity and catalytic activity for ...

2021年10月22日 · 该团队选择了由 zr-btb组成的超薄 mof 纳米片作为嫁接 amp 的理想平台。 这种二维 MOF 由六连接的 Zr簇和羧酸盐 BTB 构成，合成过程中水的参与显著阻碍 Zr-BTB 层的堆积，导致了纳米片的形成。

2019年4月9日 · An ultrathin MOF nanosheet-based material, Zr-BTB (BTB = 1,3,5-tris(4-carboxyphenyl)benzene), is initially constructed by connecting Zr 6-clusters with the tritopic carboxylate linker. Surface modification of the Zr-BTB structure was realized through the attachment of porphyrin-based carboxylate ligands on the coordinatively unsaturated Zr ...

2024年4月2日 · In/Zr-BTB nanosheets inherit the stable structure from Zr-BTB and strengthen the catalytic performance due to the introduction of highly catalytic species indium via metal-ion exchange. The thickness and areal mass loading of the modified layer are only 260 nm and 0.011 mg/cm 2, respectively.

- 通过连续计时电流测试和结构表征（PXRD、SEM、拉曼光谱和UV-Vis吸收光谱），评估了催化剂Zr-BTB@Hemin-THBA的长期稳定性。 总结 1. 本文展示了一种基于铁卟啉的2D-MOF作为在中性pH条件下将亚硝酸盐还原为氨的高效电催化剂。 2.

2023年12月10日 · 延长苯系物侧链烷烃长度，降低纳米片极性，增强纳米片与客体分子之间的疏水相互作用，丙苯和戊苯分子诱导zr-btb-p-c 3 和zr-btb-p-c 5 纳米片层间主要形成规整堆积，规整比例分别为64.8%和93.3%。计算表明，材料中出现的角度在具有区域能量最低值，符合热力学 ...