相当于用NO2作为催化剂，O2将SO2氧化为SO3，这是过去工业上制取硫酸的一种重要方法的基本原理，叫做“铅室法制硫酸”。 但实际上，真正的反应要复杂一些，部分NO2与SO2反应后，生成NO和SO3，那么只要混合气体不十分干燥，也就是混有水蒸气，就会发生下列反应：

2022年4月6日 · Herein, we report a NO 2 dimerization facilitated high performance SO 2 /NO 2 separation on a SSZ-13 zeolite membrane. The NO 2 dimerization is triggered by temperature and pressure to form N 2 O 4 with big molecular size, and N 2 O 4 diffusion into the zeolite pore is inhibited on the basis of size exclusion, leading to high separation ...

2020年6月5日 · Here we show evidence from field observations of a haze event that rapid oxidation of SO 2 by nitrogen dioxide (NO 2) and nitrous acid (HONO) takes place, the latter producing nitrous oxide...

2021年9月30日 · Our results indicate that oxidation of SO 2 by NO 2 at aerosol surfaces may be an important source of sulfate aerosols under polluted haze conditions. Atmospheric sulfate aerosol formation from...

2025年2月18日 · Here, using an aerosol optical tweezer and Raman spectroscopy, we show that the multiphase SO2 oxidation by NO2 is accelerated for two-order-of-magnitude by a copper catalyst.

2022年2月22日 · The separation of NO 2 and SO 2 is a key process step to enable practical deployment. This work proposes SO 2 separation from NO 2 using chabazite zeolite (SSZ-13) membranes and provides insights into the feasibility and advantages of this process using molecular simulation.

A new sulfate formation pathway via synergistic reactions between SO 2 and NO 2 on mineral oxides was proposed. The heterogeneous reactions of SO 2 and NO 2 on CaO, α-Fe 2 O 3, ZnO, MgO, α-Al 2 O 3, TiO 2, and SiO 2 were investigated by in situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (in situ DRIFTS) at ambient temperature.

In this paper, we researched the gas-phase reaction of SO 2 with NO 2 using the density functional theory (DFT) method. The different number of water molecules is added to the reaction so as to investigate the role of water molecules in the oxidation reaction. In addition, the effect of NH 3 in the oxidation reaction also is considered. 2.

Bài 7.23 trang 30 Sách bài tập Hóa học 11: Xét phản ứng giữa NO 2 và SO 2 trong không khí ô nhiễm sulfur dioxide: NO2 ( g) +SO2 ( g) → NO(g) +SO3 ( g) NO 2 g + SO 2 g → NO g + SO 3 g. Tính biến thiên enthalpy của phản ứng và cho biết phản ứng trên là toả nhiệt hay thu nhiệt.

2013年12月13日 · 某化学学习小组为探究NO2和SO2的反应，特进行如下实验（如下图所示）。 （1）图1两集气瓶中______（填‘上’或‘下’）瓶颜色深。 （2）图2中反应的现象是______... 展开