Effective separation of acetylene from carbon dioxide via …
2023年11月1日 · At 298 K and 1 bar, PCN-200 demonstrates a high selectivity (6.4) towards acetylene over carbon dioxide, and this separation performance is validated through dynamic …
通过微孔金属有机框架中的相应吸附有效分离 ... - X-MOL
在此，我们报道了一种超微孔金属有机框架pcn-200，它具有狭窄的之字形一维通道，尺寸约为4.5 Å。 PCN-200的孔表面具有许多对称分布的不配位氧极性位点，有利于乙炔分子（57.0 kJ mol …
Rational design of metal–organic frameworks with anticipated porosities ...
2014年2月14日 · Unlike any high-enthalpy adsorption interactions between CO 2 and frameworks, the CO 2 selectivity of PCN-200 is attributed to the presence of polar pockets with appropriate …
Construction of hexanuclear Ce(III) metal−porphyrin frameworks …
2021年8月15日 · Ce-PCN-224 MOF is synthesized composed of hexanuclear Ce (III) clusters and 5,10,15,20-tetrakis (4-carboxyphenyl)porphyrin (TCPP) linkers. The structure of Ce-PCN-224 …
Low-energy selective capture of carbon dioxide by a pre-designed ...
2012年9月24日 · Single-molecule trap: Easy activation of the water-stable metal-organic framework PCN-200 provides a new route to low-energy selective CO (2) capture through …
Angewandte Chemie International Edition - Wiley Online Library
2012年9月3日 · Single‐molecule trap: Easy activation of the water‐stable metal–organic framework PCN‐200 provides a new route to low‐energy selective CO 2 capture through …
Effective separation of acetylene from carbon dioxide via …
At 298 K and 1 bar, PCN-200 demonstrates a high selectivity (6.4) towards acetylene over carbon dioxide, and this separation performance is validated through dynamic breakthrough …
PCN-200|UMCM-1|UiO-66（Zr）金属材料_材料-西安瑞禧生物科 …
2019年11月4日 · pcn-200|umcm-1|uio-66(zr)金属材料. 瑞禧生物科技有限公司于金属有机骨架材料（包括纳米粒子复合物、量子点复合物、脂质体、胶束等）的*学应用与技术开发，并已在、 …
(a) The single crystal structure of PCN-200. The yellow spheres ...
Unlike any high-enthalpy adsorption interactions between CO 2 and frameworks, the CO 2 selectivity of PCN-200 is attributed to the presence of polar pockets with appropri- ate size to …
Effective separation of acetylene from carbon dioxide via …
2023年11月1日 · In this study, we report an ultramicroporous MOF, PCN-200, which exhibits commensurate adsorption of C 2 H 2 for efficient separation of C 2 H 2 /CO 2 mixture. Due to …