2015年4月28日 · We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crysta

2018年3月26日 · Our group integrated the Ti-cluster and photosensitizing porphyrinic linker into a MOF named PCN-22. (51) As a proof of concept, PCN-22 was employed as a photocatalyst for an alcohol oxidation reaction. Later, the Zr-porphyrin MOFs, PCN-222 (also known as MOF-545) and MOF-525, were also investigated as a photocatalyst for CO 2 reduction. (135)

PCN-222（MOF-545）是近年来研究较多的一种具有一维孔道结构的三维卟啉MOFs材料，其孔道的理论直径可以达到3.7nm，由Zr6集团簇与四羧基卟啉分子通过配位键连接形成。

2020年3月12日 · Nanorods of PCN-222, a large-pore, zirconium-based porphyrinic metal–organic framework (MOF), have been prepared through coordination modulation—controlled crystal growth through competing monodentate ligands known as modulators—for incorporation into reverse osmosis thin-film nanocomposite (TFN) membranes.

2018年3月15日 · The first porphyrin-based Ti-MOF, PCN-22, was synthesized from reaction between the preformed Ti 6 O 6 (OiPr) 6 (abz) 6 clusters and tetrakis (4-carboxyphenyl)-porphyrin (TCPP) ligands under solvothermal condition [77].

2019年8月8日 · In this paper, we describe a new, efficient, and general method for the synthesis of a range of metalated PCN-222 structures in one pot. The protocol allows a variety of these materials to be obtained in a simple and fast manner.

2023年4月15日 · Here, we synthesized, characterized, and examined the efficiency of PCN-222 (Fe), a new porous metal organic framework (MOF) with high water stability, for adsorptive …

2020年9月1日 · PCN-22 and DGIST-1 can convert benzyl alcohol to benzaldehyde under visible light. Yuan et al revealed that PCN-22, the smallest pure carboxylate-based Ti-MOF reported to date, can promote the alcohol oxidation reaction converting benzyl alcohol to benzylaldehyde under visible-light irradiation (conversion rate of 28% after 2 h) (Fig. 8 f) [130].

描述：采用连续沉积法，将低成本的CH3NH3PbI3 (MAPbI3)钙钛矿QDs包裹在 铁卟啉基MOF PCN-221 (Fex)的孔隙中，构建了一系列 MAPbI3@PCN-221 (Fex) (x = 0~1)复合光催化剂。

2015年6月15日 · We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals.