Pivotal role of reversible NiO6 geometric conversion in oxygen ...
Oct 26, 2022 · In contrast to the traditional AEM and LOM, the proposed light-triggered coupled oxygen evolution mechanism requires the unit cell to undergo reversible geometric conversion …
北科大《AFM》：调控NiO6八面体和价态实现NiO的多重电子相变 …
镍基3d轨道关联氧化物 （例如 稀土镍酸盐 （ReNiO3）、 氧化镍 （NiO）和 无限层镍酸盐）中异常复杂的轨道构型和多个 电子相变，开辟了调节材料的新范例特性突然超越了传统半导体。 …
Unraveling the effect of local dopant environment on NiO6 …
May 5, 2024 · Detailed X-ray adsorption fine-structure spectroscopy (XAFS) analysis reveals a volcano-like relationship between the V dopant content and the extent of NiO 6 octahedron …
可逆 NiO6 几何转化在析氧过程中的关键作用,Nature - X-MOL
与传统的 AEM 和 LOM 相比，所提出的光触发耦合析氧机制要求晶胞在八面体 (NiO 6 ) 和 方形平面 (NiO 4 ) 之间进行可逆几何转换，以实现电子态（在费米能级附近）在整个氧气释放过程中 …
In contrast to the traditional AEM and LOM, the proposed light-triggered coupled oxygen evolution mechanism requires the unit cell to undergo reversible geometric conversion between …
北科大《AFM》：调控NiO6八面体和价态实现NiO的多重电子相变
Aug 19, 2023 · 镍基3d轨道关联氧化物（例如稀土镍酸盐（ReNiO3）、氧化镍（NiO）和无限层镍酸盐）中异常复杂的轨道构型和多个电子相变，开辟了调节材料的新范例特性突然超越了传统 …
Light Inducing the Geometric Conversion of NiO6 to Trigger a …
Nov 21, 2022 · Recently in Nature, Xue and colleagues revealed a new OER mechanism, coupled oxygen evolution mechanism (COM), which involves a switchable metal and oxygen redox …
可逆NiO6几何转化在析氧过程中的关键作用 - 科学网
Oct 26, 2022 · 新加坡国立大学Xue Junmin团队报道了可逆NiO6几何转化在析氧过程中的关键作用。 相关研究成果于2022年10月26日发表于国际一流学术期刊《自然》。 通过改变费米能级周 …
Multiple Electronic Phase Transitions of NiO via Manipulating the NiO6 …
Jun 6, 2023 · The adjustment in band gap of NiO with t2g6eg2 orbital configuration is achieved via establishing biaxial tensile or compressive interfacial strains that increase or reduce the …
Updating the sub-nanometric cognition of reconstructed ... - Nature
Mar 30, 2025 · We reveal the sub-nanometric structural difference of NiO6 unit with a regular distortion in the reconstructed active phase NiOOH, codetermined by the geometric (bond …
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