
Defect Tailoring in the Metal–Organic Framework Cu (BDC-NH2) …
Mixed-linker metal–organic frameworks of Cu (BDC-NH 2) have been fabricated in which the 2-aminoterephthalic acid (BDC-NH 2) linker has been partially replaced by 3,5-pyridinedicarboxylic acid (PYDC) without obviously changing the crystal structure.
Zn-(BDC) and Zn-(BDC)-NH 2 MOFs: Novel Photocatalysts for ...
The paper reports the development of nanostructures of organic-metallic frameworks (MOFs) in the form of Zn(BDC) and Zn(BDC)-NH2 as potent macroporous photocatalysts for desulfurization of aromatic hydrocarbons (dibenzothiophene) in fuels.
Electrocatalytic performance of NiNH 2 BDC MOF based ... - Nature
2021年6月28日 · Present work comprehensively investigated the electrochemical response of Nickel-2 Aminoterephthalic acid Metal–Organic Framework (NiNH 2 BDC) and its reduced graphitic carbon (rGO)...
Electrochemical ammonia oxidation on terephthalic acid framework (BDC …
2024年11月15日 · A terephthalic framework, Ni-BDC-NH 2, was used to synthesize the nickel nanoparticles and nanoclusters on-site encapsulated within mesoporous carbon nanoflakes (NiO/Ni/CNF) for ammonia electrolysis.
Bismuth Metal–Organic Framework/Carbon Nanosphere …
2023年5月3日 · An amino-functionalized bismuth metal–organic framework (Bi-BDC-NH 2) composited with nitrogen-doped mesoporous carbon nanosphere (NMCS) was prepared to fabricate a Bi-BDC-NH 2 @NMCS electrochemical sensor …
Excellent laccase-like activity of melamine modified Cu-NH2-BDC …
2024年8月3日 · In this work, an N-rich melamine (Mel) was introduced into the Cu-MOF composed of copper(II) nitrate and 2-aminoterephthalic acid (Cu-NH2-BDC-Mel) to mimic the laccase, which enzyme-like activities were assessed and applied in sensing analyses toward several phenols and amines.
Palladium Schiff base complex-modified Cu(BDC-NH2) …
In this study, the synthesis of a novel functionalized metal–organic-framework (MOF) [Cu (BDC-NH 2)@Schiff-base-Pd (II)] catalyst via post-synthetic modification of Cu (BDC-NH 2) is reported.
Design and Multiple Applications of Mixed-Ligand Metal–Organic ...
2022年3月14日 · Herein, we revealed the factors that affect the emission in mixed-ligand metal–organic frameworks (MOFs) with the combination of terephthalic acid (BDC), 2-aminoterephthalic acid (BDC-NH2), and 2,5...
Amino-functionalized Cu metal–organic framework nanosheets as ...
Here, we report a simple and benign method to successfully fabricate amino-functionalized Cu metal–organic framework (NH2–Cu-MOF) nanosheets. After synthesizing Cu2O nanocubes, they were mixed with organic ligand 2-aminoterephthalic acid (NH2BDC) solution at room temperature for 4 hours to form NH2–Cu-MOF na
Hetero MOF‐On‐MOF of Ni‐BDC/NH2‐MIL‐88B(Fe) Enables …
2024年2月4日 · In this work, we described the fabrication of a hybrid MOF-on-MOF heterojunction with unique interfacial chemical bonds by coupling NM88B (Fe) with Ni-BDC using a trivial solvothermal route.
(a) PXRD analysis of Zn-BDC-NH 2 , the calculated ... - ResearchGate
In this work, a nano Zn-BDC-NH2 encoded MOF was effectively synthesized using the co-surfactants strategy and characterized for the curcumin adsorption.
Effect of Cu (BDC-NH2) MOF deposited on Cu/Cu2O electrode …
2021年1月1日 · The present work reports the development of Cu/Cu 2 O- Cu (BDC-NH2) electrode, prepared by electrochemical deposition using the ligand 2-amino-1,4-benzenedicarboxylic acid and copper ion (II) produced in situ, and its application in CO2 reduction in aqueous medium.
An amino-decorated dual-functional metal–organic framework for highly ...
2016年9月9日 · A 3D Zn(ii)-based metal-organic framework, [Zn2(TPOM)(NH2–BDC)2]·4H2O (NH2–Zn-MOF, TPOM = tetrakis(4-pyridyloxymethylene)methane and NH2–BDC = 2-aminoterephthalic acid), was successfully achieved via a hydrothermal reaction.
A facile approach for preparing Zr-BDC and Zr-BDC-NH2 MOFs …
2021年5月10日 · Here, we proposed a facile solvothermal method for preparing two kinds of MOFs with Zr as a central metal, i.e. Zr-BDC and Zr-BDC-NH2. The synthesized MOFs were characterized using XRD, FTIR, SEM, TEM, and BET.
Preparation and electrochemical characteristics of metal–organic ...
2023年2月11日 · In this study, Metal–Organic Framework [Zn (NH 2 -bdc) (4,4′-bpy)] was synthesized using the hydrothermal method, and the porous carbon ZNBC-T-A was synthesized through chemical activation with Metal–Organic Framework and ZnCl 2 as the precursor and the activator, respectively.
Fabrication of Cu(BDC)0.5(BDC-NH2)0.5 metal-organic framework …
2021年5月1日 · In this work, we have fabricated a mixed ligand MOF, Cu (BDC) 0.5 (BDC-NH 2) 0.5 for adsorptive removal of H 2S gas in column studies. The synthesized MOF was characterized by various microscopic and spectroscopic techniques to evaluate their structural, functional, and optical characteristics.
A Two Step Postsynthetic Modification Strategy: Appending Short …
2021年7月15日 · The best performing material, TAEA-appended-Zn 4 O(NH 2-BDC) 1.2 (BrAcNH-BDC) 1.8, exhibits a zero-coverage isosteric heat of CO 2 adsorption of −62.5 kJ/mol, a value that is considerably higher than the one observed for the parent framework, −21 kJ/mol.
A Two Step Postsynthetic Modification Strategy: Appending
2021年7月21日 · Functionalizing metal-organic frameworks (MOFs) with amines is a commonly used strategy to enhance their performance in CO 2 capture applications. As such, in this work, a two-step strategy to covalently functionalize NH 2 -containing MOFs with short chain polyamines was developed.
A facile approach for preparing Zr-BDC and Zr-BDC-NH 2 MOFs …
2022年6月1日 · Here, we proposed a facile solvothermal method for preparing two kinds of MOFs with Zr as a central metal, i.e. Zr-BDC and Zr-BDC-NH2.
(PDF) Palladium Schiff base complex-modified Cu(BDC-NH 2 ) …
2023年3月13日 · In this study, the synthesis of a novel functionalized metal-organic-framework (MOF) [Cu (BDC-NH2)@Schiff-base-Pd (ii)] catalyst via post-synthetic modification of Cu (BDC-NH2) is...