2020年10月8日 · Post-synthetic modification (PSM) of metal–organic framework (MOF) compounds is a useful technique for preparing new MOFs that can exhibit or enhance many of …

2021年8月16日 · Once a metal center is incorporated into a MOF, by either direct synthesis or PSM, these metal centers can be further modulated using PSM. For example, Doonan et al. …

2023年11月1日 · 合成后修饰（PSM）是通过在 MOF 合成后修饰金属簇或配体，将功能化学基团引入金属有机框架（MOF）中的有效方法。 PSM能够将各种功能性化学基团纳入框架中，而 …

2023年9月15日 · In-situ modification and post-synthetic modification (PSM) are two efficient ways to manipulate MOF structures. Comparing these two approaches, PSM is more appealing as it …

2023年11月1日 · Post-synthesis modification (PSM) is an efficient means to introduce functional chemical groups into metal–organic frameworks (MOFs) by modifying metal clusters or ligands …

The surface of MOF crystals can be functionalized using two methods: 1) coordination modulation refers to methods where the MOF is functionalized during synthesis, and 2) post-synthetic …

While there are myriad ways to construct metal–organic framework (MOF) based catalysts, the introduction of catalytic functionality via covalent post-synthesis functionalization (PSM) offers …

This review focuses on the current advancements of four PSM methods to construct functionalized MOFs for photocatalytic applications in water splitting, CO 2 reduction, organic …

2022年4月4日 · Thereby, their predesigned structures can undergo post-synthetic modifications (PSMs) to introduce new functional groups and properties by modifying the linker, metal node, …

This clever approach provided a new method for synthesizing MOF-templated polymers through simple modulation of covalent PSM in conjunction with MOF stability. These studies show that …