MOF-COF框架材料 - 知乎 - 知乎专栏
金属有机框架(mof)和共价有机框架(cof)材料是两种多孔的晶态材料，具备较大的比表面积、高的孔隙率，结构合成修饰方法丰富,因此在析氢、析氧、co2还原、有机物降解、气体分离等多个方面都有应用前景。但mof、cof自…
Integration of metal-organic frameworks and covalent organic frameworks ...
2021年7月7日 · In this review, we provide an overview of significant progress in the design and synthesis of MOF/COF hybrids, including MOF@COF, COF@MOF, MOF + COF, C-MOF, and COF-in-MOF, and their various applications in catalysis, gas adsorption, sensing, energy storage, and photodynamic therapy.
mof/cof 复合材料主要有两种合成策略，第一种策略表示为“cof on mof”，即通过将制备好的 mof 引入合成cof 的单体来制备mof/cof 复合物。这种方法是合成mof/cof 复合材料中最广泛使用 的方法。
MOF（有机金属框架）与COF有什么应用？ - 知乎
MOF（Metal-Organic Frameworks，有机金属框架）和COF（Covalent Organic Frameworks，共价有机框架）是两类新兴的多孔材料。 MOF由金属离子和有机配体通过配位键连接形成，COF则完全由轻元素（如碳、氢、氮、氧）通过共价键连接构成。
Metal–organic frameworks and covalent organic frameworks as …
2022年8月22日 · In this Review we survey the molecular sieving behaviour of metal–organic framework (MOF) and covalent organic framework (COF) membranes, which is different from that of classical zeolite...
化材院宁国宏/李丹团队︱Acc. Chem. Res.封面文章：共价金属有机 …
2025年3月16日 · 由于连接方式的性质，mof和cof有着各自的特点。例如，mof因配位键较弱，化学稳定性不足；cof虽稳定性高，但缺乏金属活性位点。因此，融合mof和cof化学而发展的新型晶体多孔材料，即共价金属有机框架（cmof），有望融合mof和cof的优点。
Emerging MOFs, COFs, and their derivatives for energy
2025年2月3日 · Emerging porous framework materials such as metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), recognized as exemplary crystalline porous materials, exhibit potential in energy and environmental applications due to their high specific surface area, adjustable pore sizes and structures, permanent porosity, and customizable fu...
Research Progress on the Mechanisms of MOF/COF and
5 天之前 · The rapid depletion of fossil fuels and growing concerns about environmental issues is driving the demand for renewable energy storage systems. Zinc−i…
Crystal‐Facet‐Controlled Internal Electric Field in MOF/COF ...
2025年2月20日 · Herein, for the first time, we report a rational control of the internal electric field in MOF/COF heterojunction by engineering the crystal facet of MOFs to achieve enhanced photocatalytic overall water splitting (OWS) activity. A new type of covalently connected MOF/COF photocatalytic system based on NH 2-MIL-125(Ti) and TpBpy-COF was ...
Converging the Complementary Traits of Metal–Organic …
The MOF@COF composite, MOF@COF-Pd, was employed as a catalyst for C-C coupling reactions. This MOF@COF composite contains a large number of Schiff bases within the structure, where Pd forms coordination bonds. This enables high stability and excellent dispersion of Pd, making it suitable for use as a catalyst in this organic reaction.