2021年7月13日 · However, Mg-MOF-74 thin films present significant challenges in demonstrating large-scale coatings. Herein, we demonstrate for the first time high-quality Mg-MOF-74 films synthesized via a vapor-assisted crystallization (VAC) process.

In this work, metal oxide nanoparticles are used to stabilize Pickering emulsions and in-situ transformed into MOFs to prepare hierarchically porous Mg-MOF-74 monoliths. The obtained materials exhibit large surface area of 659 m 2 /g and high MOF loading of ∼77 %.

2017年10月1日 · Mg-MOF-74 is a metal organic framework with the highest CO 2 adsorption capacity of any porous material. Therefore, it has been suggested for CO 2 separations as both an adsorbent and incorporated into membranes. Design of the Mg-MOF-74 crystal morphology is important to expand the applicability of the material.

本文通过系统研究合成参数对mg-mof-74晶体尺寸和形态的影响，成功实现了从纳米到微米尺寸范围内的精确调控。 特别是通过改变水量，首次合成了具有高长宽比的纳米级片状Mg-MOF-74晶体。

2023年11月15日 · The crystal structure, morphology and pore size of Mg-MOF-74 could be precisely regulated by the β/α value and molecular size of the reaction solvent, and the highest performing Mg-MOF-74 exhibited a CO 2 adsorption capacity of 7.38 mmol/g.

2025年1月9日 · In this work, Mg-metal–organic frameworks (MOF) is incorporated into a polyethylene oxide (PEO)-based polymer solid electrolyte, leading to the in-situ formation of LiF and other compounds at the electrolyte interface.

2021年12月15日 · Bimetallic metal–organic frameworks (MOFs) containing two different inorganic metal nodes exhibited enhanced properties in CO 2 adsorption and catalytic conversion compared with the corresponding monometallic MOFs. In this work, the novel bimetallic Zn/Mg-MOF-74 with different ratios of Zn/Mg was synthesized successfully by a facile one-pot method.

与相应的单金属 MOF 相比，含有两种不同无机金属节点的双金属金属有机骨架 (MOF) 在 CO 2吸附和催化转化方面表现出增强的性能。在这项工作中，通过简便的一锅法成功合成了具有不同 Zn/Mg 比例的新型双金属 Zn/Mg-MOF-74。

2025年3月6日 · This work offers insights into for the design and controllable preparation principles of the adsorption and screening of bi-functional Mg-based MOFs-based carbon capture materials and provides a fundamental basis for obtaining MOF-based carbon capture materials with improved efficiency.

2021年3月11日 · The results demonstrate that a large amount of nanosized Mg-MOF-74 particles is incorporated into the pores of mesocellular siliceous foams (MCFs) without remarkable aggregation and the composites possess microporous …