Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

Innovation in organic chemistry and chemical biology through the development u0003of general catalysis concepts and their application to u0003complex targets. The pursuit of new concepts …

2020年12月14日 · A number of recoverable imidazolidinones have been reported in asymmetric Diels-Alder reactions. In this review, we have summarized the reports on reusable and …

2022年5月25日 · MacMillan催化剂 type 1（ α-氨基酸衍生的咪唑烷酮）可以作为不对称有机催化剂高对映选择性的催化 Diels-Alder反应。这种催化剂可以非对映选择性地催化很多类型的反应。

2014年1月1日 · Highly enantioselective and general asymmetric organocatalytic Diels–Alder reaction using α-amino acid-derived imidazolidinones (of type 1) as catalysts. The first …

MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and …

In this work, we explored the use of commercially available MacMillan’s catalysts with the target to accelerate the reaction and achieve high yield and enantiomeric ratio (e.r.) by fine-tuning the …

Highly enantioselective and general asymmetric organocatalytic Diels-Alder reac-tion using D-amino acid-derived imidazolidinones (of type 1) as catalysts. The first generation of MacMillan …

2021年10月19日 · 手性咪唑烷酮类有机催化剂是戴维•麦克米伦教授（David MacMillan）于 2000 年开发的一种稳定、环境友好的小分子有机催化剂，这种催化剂能在温和条件下高对映选择性 …

In this work, we explored the use of commercially available MacMillan’s catalysts with the target to accelerate the reaction and achieve high yield and enantiomeric ratio (e.r.) by fine-tuning the …