An isocyanide (also called isonitrile or carbylamine) is an organic compound with the functional group – N+≡C−. It is the isomer of the related nitrile (–C≡N), hence the prefix is isocyano. [1] . …

2013年9月19日 · Ivar Ugi (1930-2005) discover many important chemistry of isocyanides, e.g., the Ugi reaction. Isocyanide is a useful synthetic building block. Being stable carbenes, …

2023年7月20日 · Isocyanides, also known as Isonitriles or Carbylamines, are any of an organic compound with the molecular formula R – N ≡ C, where R is a combining group derived by the …

Corey et al. have reported the total synthesis of 7,20-diisocyanoadociane. The introduction of both isocyano groups was achieved by treatment of the bistrifluoroacetate (8) with TMS-CN in the …

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2020年6月10日 · Here, the authors report their discovery of a noncovalent halogen bond involving the isocyano carbon lone pair, which results in adducts with strongly reduced isocyanide odor.

2014年1月1日 · Polyisocyanides and polyisocyanates are both obtained by the polymerization of monomers with a highly reactive functional group, isocyanide and isocyanate, respectively, …

isocyanide, any of a class of organic compounds having the molecular structure R―N + ≡ C, in which R is a combining group derived by removal of a hydrogen atom from an organic …

2024年4月6日 · By exploiting the different nucleophilicity of aromatic and aliphatic isocyanides, we selectively react aliphatic isocyano groups while preserving aromatic ones in Passerini and Ugi …

2022年4月5日 · In this work, we report the recognition of the (isocyano group)···Pt II interactions where the isocyano nitrogen acts as a π-hole donor toward a d z 2-orbital of the Pt II center …