
Carbonylation of ammonia by gaseous FCO+. A G2 and Rice …
1999年3月15日 · The detailed mechanism of the gas-phase carbonylation of NH 3 by FCO + with formation of H 2 NCO + and HF has been theoretically investigated by G 2 and Rice …
Health & Environmental Research Online (HERO)
4 天之前 · Gaseous FCO+ ions from the ionization of mixtures of nitrogen trifluoride and carbon monoxide execute selective and efficient CO-functionalization of the C-H bonds of benzene …
The millimeter-wave spectra of FN2+ and FCO+ and ab
1992年5月1日 · Isoelectronic with FN2 and FCO+ is FCN, which has been extensively studied by microwave and IR spectroscopy; this molecule serves as a benchmark for the present …
Ionic Fluorination of Carbon Monoxide as a Route to Gasphase ...
1996年5月1日 · Combining the latter F+ transfer with the independently observed fluoride-ion abstraction by FCO+ from NF3 results in a catalytic cycle in which gaseous NF+2 ions …
FCO+ - NIST Chemistry WebBook
FCO+. Formula: CFO + Molecular weight: 47.0080; CAS Registry Number: 38264-00-5; Information on this page: Notes; Other data available: Vibrational and/or electronic energy …
Ionic Fluorination of Carbon Monoxide as a Route to Gasphase ...
Inert C-H and N-H bonds can be activated by FCO+ obtained from the ionic fluorination of carbon monoxide. Efficient and selective carbonylation of benzene, toluene, and ammonia is observed …
Ionic Fluorination of Carbon Monoxide as a Route to Gasphase ...
Combining the latter F + transfer with the independently observed fluoride-ion abstraction by FCO + from NF 3 results in a catalytic cycle in which gaseous NF +2 ions promote the conversion of …
Carbonic difluoride (CF20) and fluorooxomethyl radical (FCO) are important intermediates in the oxidative degradation of many fluorinated compounds. These species are involved in the...
Carbonylation of ammonia by gaseous FCO+. A G2 and Rice …
1999年3月15日 · The detailed mechanism of the gas-phase carbonylation of NH3 by FCO + with formation of H 2 NCO + and HF has been theoretically investigated by G2 and Rice …
Reactions of gaseous halocarbonyl cations with aromatic compounds ...
2003年8月1日 · The mass-selected halocarbonyl cations FCO+, ClCO+, and BrCO+ were reacted with benzene, thiophene, pyrrole, and furan and a few of their alkyl derivatives to evaluate the …
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