2022年12月1日 · The alkynyl ligands induce 1D growth via the active surface growth mechanism, which was previously only applicable to the thiolated ligands. The binding mode of the alkynyl …

A highly enantioselective catalytic addition of alkynyl zinc reagents to simple ketones was accomplished by the Chan group (Figure 15). 22 They initially examined the system using …

2 天之前 · In this study, we synthesized a series of chiral Au(I) complexes using BINAP ligands and alkynyl ligands, incorporating amide structures and alkoxy groups into the alkynyl ligands …

2024年11月1日 · Alkynyl and thiolate protected Au 22 clusters are the most extensively studied NIR materials. Early in 2014, Xie group reported the PLQY of Au 22 (SG) 18 can reach 8% …

2011年8月1日 · Reactions on the alkynyl group of alkynyl-substituted 1,2-diazines have been incorporated starting from CHEC-II(1996) <1996CHEC-II(6)1>. Double nucleophilic additions …

2019年4月1日 · Alkynyl chemistry based on TMC was championed by our group: reaction between [Ni(TMC)X] + (X = Cl or OTf) and LiC 2 R yielded a variety of [Ni(TMC)(C 2 R)] + type …

2016年7月21日 · We further found that 7-alkynyl-fucose is mainly incorporated into N-glycans at the core position. These results suggest that 7-alkynyl-fucose is a probe with the highest …

2024年8月15日 · As more and better synthetic methods have been developed, 5-alkynyl-1,2,3-triazoles have become increasingly important due to the biological properties found in this …

2025年3月1日 · Six alkynyl PhC C-ligands arranged in μ 3-η 1,η 1,η 1 coordination mode each link three silver atoms in triangle form (Fig. 3 a). The above triangles hexamerizate using …

2024年11月1日 · Recently, alkynyl molecules have been emerging as a new type of protecting ligand, forming a unique class of ligand-protected metal nanoclusters [35,36,44,45]. This …