
醛亚胺 - 百度百科
醛亚胺是指醛与伯胺在一定条件下发生亲核加成反应后消除一分子水生成的产物,一般可以用通式RCH=NR1(R、R1可以是芳基也可以是烷基)表示。 醛亚胺是亚胺的一种形式,亚胺也叫做 …
Imine - Wikipedia
In organic chemistry, an imine (/ ɪˈmiːn / or / ˈɪmɪn /) is a functional group or organic compound containing a carbon – nitrogen double bond (C=N). The nitrogen atom can be attached to a …
Selective Aliphatic Aldimine Formation and Stabilization by a ...
4 天之前 · Imines and enamines are useful intermediates in biochemical aldol-type reactions since their acid/base characteristics are accessible near neutrality. However, the generation of …
Imines – Properties, Formation, Reactions, and Mechanisms
2022年3月7日 · Imines are the nitrogen analogues of aldehydes and ketones, containing a C=N bond instead of a C=O bond. They are formed through the addition of a primary amine to an …
Aldimine - an overview | ScienceDirect Topics
Aldimines bearing an N - p -methoxyphenyl (PMP) group were extensively employed as acceptors in the proline-catalyzed direct Mannich reaction. One of the problems associated with the N …
A General Aminocatalytic Method for the Synthesis of Aldimines
2013年12月20日 · A general and efficient biomimetic method for the synthesis of aldimines from aldehydes and compounds bearing the NH 2 group in the presence of pyrrolidine as a catalyst …
Mechanistic Understanding of Base‐Catalyzed Aldimine…
2021年1月23日 · Aldimine/ketoamine condensations are basic reactions in chemical synthesis. Herein a density functional theory (DFT) study was performed to characterize the mechanism …
通用方法 | Aldimine化合物的制备_反应 - 搜狐
2021年4月8日 · Aldimine化合物是取代亚胺类化合物,包括N-磺酰基亚胺、N-亚磺酰基亚胺,N-膦酰基亚胺,N-烷基和N-芳基亚胺等等。 这类化合物在有机合成和药物化学上具有重要应用。
Structural insights into the mechanism of internal aldimine formation ...
2019年11月1日 · Formation of the internal aldimine (LLP) is the first regulatory step that activates pyridoxal 5′-phosphate (PLP) dependent enzymes. The process involves a nucleophilic attack …
aldimine (CHEBI:33271) - EMBL-EBI
Imines derived from aldehydes, i.e. compounds having the structure RCH=NR. This entity has been manually annotated by the ChEBI Team. This service is an Elixir Core Data Resource. …