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Host–guest chemistry - Wikipedia
Host–guest chemistry encompasses the idea of molecular recognition and interactions through non-covalent bonding. Non-covalent bonding is critical in maintaining the 3D structure of large molecules, such as proteins and is involved in many biological processes in which large molecules bind specifically but transiently to one another.
Applications of macrocycle-based solid-state host–guest chemistry
2023年10月2日 · Extending host–guest chemistry from solution to the solid state results in complexes that are generally more robust, enabling easier processing and broadened applications. Macrocyclic...
Supramolecular Chemistry: Host–Guest Molecular Complexes
In host–guest (HG) interaction, distinctive structural complexes development occurs via non-covalent associations [1]. There is a growing curiosity in executing supramolecular HG structures for assembling organic solvents and aqueous solutions on compact planes [2].
Unveiling host–guest–solvent interactions in solution by …
2022年5月17日 · By addressing this highly critical question, we describe here a novel protocol for examining the host–guest–solvent interactions in solution by elucidating the structures of gas phase host...
An overview from simple host–guest systems to progressively …
2021年11月17日 · In this perspective, we present a stimulating overview, discussing simple host–guest systems to complex supramolecular assemblies in a systematic manner, aiming to encourage future researchers in this fascinating area of supramolecular chemistry to develop advanced supramolecular materials with superior functionalities, for their deployment ...
Symmetry-breaking host–guest assembly in a hydrogen-bonded …
2023年1月11日 · In this study, we report the symmetry-breaking self-assembly of a defined C1 -symmetric supramolecular structure from an Oh -symmetric hydrogen-bonded resorcin [4]arene capsule and C2 -symmetric...
Unveiling host–guest–solvent interactions in solution by …
By addressing this highly critical question, we describe here a novel protocol for examining the host–guest–solvent interactions in solution by elucidating the structures of gas phase host–guest complexes. We employ the perm β-CD/LysH + complex as a prototypical host–guest system to advance the scheme.
Recent advances and perspectives of supramolecular host-guest systems ...
2024年9月1日 · Supramolecular host-guest chemistry is a major branch of supramolecular chemistry that focuses on the study of non-covalent interactions between molecules. It explores the dynamic and reversible binding of host and guest molecules, typically within the confines of a well-defined cavity or binding site as illustrated in Fig. 1.
Aqueous highly emissive host-guest systems by host enhanced ...
2020年2月1日 · In this work, we report the host-guest interactions between (E)-1-benzyl-4-(2-(pyren-1-yl)vinyl)pyridin-1-ium bromide (PVP) and cucurbit[n]uril (CB[n], n = 7, 8), which were investigated in aqueous solution by 1 H NMR, UV/Vis, fluorescence spectroscopic techniques and isothermal titration calorimetry (ITC).
Host-guest assembly triggered lower critical solution …
2024年4月1日 · In summary, we successfully constructed a supramolecular self-assembly system with dual stimulation response to temperature and light through a host-guest assembly process between an alkyl quaternary ammonium-modified azobenzene guest …