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EurekAlert!
5 个月
MOF封装提高金属纳米团簇催化性能的新机制
image: 基于配位自组装和静电相互作用,在室温和碱性水溶液条件下,Au25(Cys)18纳米团簇被封装到代表性的多金属有机框架M-MOF-74中(M = Zn、Ni、Co、Mg)。
EurekAlert!
3 年
操纵MOF中的体/受体空间排列以实现TADF
首先,主体MOF框架的限域空间和较强的配位作用可以固定D和A分子的位置和取向,获得空间分离的D和A分子,这将降低最高占据分子轨道(HOMO ...
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